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31.
以苏州太平金融大厦为工程背景,针对其大跨裙摆屋盖的风荷载作用,首先采用RNG k-ε模型模拟分析了其平均风压分布规律,以及风向变化对屋盖表面风荷载体型系数的影响;其次,引入干扰因子IF,探讨了周边建筑对大跨裙摆屋盖风荷载的气动干扰作用。结果表明:0°风向下,走廊上方屋盖两侧区域出现“上吸下顶”的叠加作用;90°风向下屋盖北侧飘带末端区域受到狭道风效应出现正压集中现象;风向变化对大跨裙摆屋盖的风荷载体型系数分布影响较大;且周围建筑物对大跨裙摆屋盖的气动干扰效应明显,主要表现为风压“遮挡效应”,而局部区域表现为风压“放大效应”。 相似文献
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33.
On the (N+1)-dimensional local fractional reduced differential transform method and its applications
Jian-Gen Liu Xiao-Jun Yang Yi-Ying Feng Ping Cui 《Mathematical Methods in the Applied Sciences》2020,43(15):8856-8866
In this paper, we generalize the (N+1)-dimensional local fractional reduced differential transform method (LFRDTM) within the local fractional derivative sense. First, we show some new properties, lemmas, theorems and corollariesfor the (N+1)-dimensional LFRDTM. Second, these new properties, lemmas and theorems can be proved immediately after. Thirdly, we used two examples to state that this approach is efficient and simple to find numerical solutions to higher dimensional local fractional partial differential equations. Finally, we can be seen that this work can be looked as an extension of the prior work. 相似文献
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由于在染料敏化太阳能电池(dye-sensitized solar cell, DSSC)中存在染料弛豫、半导体薄膜中电子与氧化态染料分子发生反应和电子在电解质中与氧化态离子复合等不利反应,利用一个更完善的DSSC载流子传输模型对电池的光电性能进行模拟就显得非常重要。为此,本文基于由多重俘获理论建立的DSSC中的包括电子、染料阳离子、碘化物和三碘化物在内的载流子传输模型,数值模拟得到了不同TiO2薄膜厚度、不同入射光强度与不同染料分子吸收系数下DSSC的J-V曲线。结果表明,随着TiO2薄膜厚度的增加,太阳能电池的短路电流密度增大,开路电压减小,光电转换效率先增大后减小。当DSSC的TiO2薄膜厚度为20 μm时,光电转换效率达到最大值7.41%,同时光电转换效率随入射光强度与染料分子吸收系数的增大均有一定程度提高,其中在吸收系数为4 500 cm-1时,光电转换效率为6.73%。以上结果可以为改进DSSC的光电性能提供理论指导。 相似文献
36.
ABSTRACTA striking feature of lyotropic chromonic liquid crystals confined in cylinder model exhibit double-twist director configurations. Evidence suggests that saddle-splay deformation is among the most important factors for the distortions of director. Previous researches limit the director to distort at a fixed plane (r-? plane) by using specific boundary conditions such as degenerate planar anchoring condition. In this work, we consider lyotropic chromonic liquid crystals confined between two coaxial cylinders with free-surface boundary conditions and Rapini-Papoular-type anchoring conditions. By using finite-difference iterative method to solve the numerical solution of Euler equation, we find that saddle-splay deformation leads to double-twist director configurations under free-surface boundary conditions, which consist of the result under degenerate planar anchoring conditions. Furthermore, at Rapini-Papoular-type anchoring conditions, saddle-splay deformation has a great influence on the director in the radial direction (r direction) and the director distorts in three-dimensional space. Remarkably, our method provides a more accurate theory basis for the measured values of saddle-splay elastic constant K24。 相似文献
37.
Leah B. Casabianca 《Magnetic resonance in chemistry : MRC》2020,58(7):611-624
The nuclear magnetic resonance (NMR) chemical shift is extremely sensitive to molecular geometry, hydrogen bonding, solvent, temperature, pH, and concentration. Calculated magnetic shielding constants, converted to chemical shifts, can be valuable aids in NMR peak assignment and can also give detailed information about molecular geometry and intermolecular effects. Calculating chemical shifts in solution is complicated by the need to include solvent effects and conformational averaging. Here, we review the current state of NMR chemical shift calculations in solution, beginning with an introduction to the theory of calculating magnetic shielding in general, then covering methods for inclusion of solvent effects and conformational averaging, and finally discussing examples of applications using calculated chemical shifts to gain detailed structural information. 相似文献
38.
The formation of a line of equally spaced particles at the centerline of a microchannel, referred as “particle ordering,” is desired in several microfluidic applications. Recent experiments and simulations highlighted the capability of viscoelastic fluids to form a row of particles characterized by a preferential spacing. When dealing with non-Newtonian fluids in microfluidics, the adherence condition of the liquid at the channel wall may be violated and the liquid can slip over the surface, possibly affecting the ordering efficiency. In this work, we investigate the effect of wall slip on the ordering of particles suspended in a viscoelastic liquid by numerical simulations. The dynamics of a triplet of particles in an infinite cylindrical channel is first addressed by solving the fluid and particle governing equations. The relative velocities computed for the three-particle system are used to predict the dynamics of a train of particles flowing in a long microchannel. The distributions of the interparticle spacing evaluated at different slip coefficients, linear particle concentrations, and distances from the channel inlet show that wall slip slows down the self-assembly mechanism. For strong slipping surfaces, no significant change of the initial microstructure is observed at low particle concentrations, whereas strings of particles in contact form at higher concentrations. The detrimental effect of wall slip on viscoelastic ordering suggests care when designing microdevices, especially in case of hydrophobic surfaces that may enhance the slipping phenomenon. 相似文献
39.
Kamonwad Ngamchuea Dr. Kristina Tschulik Shaltiel Eloul Prof. Dr. Richard G. Compton 《Chemphyschem》2015,16(11):2338-2347
Partially blocked electrodes (PBEs) are important; many applications use non‐conductive nanoparticles (NPs) to introduce new electrode functionalities. As aggregation is a problem in NP immobilization, developing an in situ method to detect aggregation is vital to characterise such modified electrodes. We present chronoamperometry as a method for detection of NP surface aggregation and semi‐quantitative sizing of the formed aggregates, based on the diffusion limited current measured at PBEs as compared with the values calculated numerically for different blocking feature sizes. In contrast to voltammetry, no approximations on electrode kinetics are needed, making chronoamperometry a more general and reliable method. Sizing is shown for two modification methods. Upon drop casting, significant aggregation is observed, while it is minimized in electrophoretic NP deposition. The aggregate sizes determined are in semi‐quantitative agreement with ex situ microscopic analysis of the PBEs. 相似文献
40.
数值修约是分析化学教学的重要内容。目前,主流分析化学教材均采用 “四舍六入五留双”数值修约规则。详细剖析了该规则中尾数与进舍条件的关系,指出“四舍六入五留双”修约规则中应采用“尾数的首位”而不是“尾数”设置进舍条件,否则存在逻辑错误。对比分析表明,“四舍六入五留双”以数字4、5和6为比较值设置的修约规则等价于GBT8170—2008国家标准中以数字5为比较值设置的进舍规则,但GBT8170—2008国家标准的进舍规则的逻辑、表述等优于“四舍六入五留双”规则。因此,建议分析化学教材采用GBT8170—2008国家标准规定的数值修约相关内容。 相似文献